Gibbs/gaussian/h-h-endiin-yyy-1b2-f-01-a-6...

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Plaintext

Entering Gaussian System, Link 0=g09
Input=h-h-endiin-yyy-1b2-f01a-631s.gjf
Output=h-h-endiin-yyy-1b2-f01a-631s.log
Initial command:
/opt/g09/l1.exe /scratch/g09/Gau-12849.inp -scrdir=/scratch/g09/
Entering Link 1 = /opt/g09/l1.exe PID= 12851.
Copyright (c) 1988,1990,1992,1993,1995,1998,2003,2009, Gaussian, Inc.
All Rights Reserved.
This is part of the Gaussian(R) 09 program. It is based on
the Gaussian(R) 03 system (copyright 2003, Gaussian, Inc.),
the Gaussian(R) 98 system (copyright 1998, Gaussian, Inc.),
the Gaussian(R) 94 system (copyright 1995, Gaussian, Inc.),
the Gaussian 92(TM) system (copyright 1992, Gaussian, Inc.),
the Gaussian 90(TM) system (copyright 1990, Gaussian, Inc.),
the Gaussian 88(TM) system (copyright 1988, Gaussian, Inc.),
the Gaussian 86(TM) system (copyright 1986, Carnegie Mellon
University), and the Gaussian 82(TM) system (copyright 1983,
Carnegie Mellon University). Gaussian is a federally registered
trademark of Gaussian, Inc.
This software contains proprietary and confidential information,
including trade secrets, belonging to Gaussian, Inc.
This software is provided under written license and may be
used, copied, transmitted, or stored only in accord with that
written license.
The following legend is applicable only to US Government
contracts under FAR:
RESTRICTED RIGHTS LEGEND
Use, reproduction and disclosure by the US Government is
subject to restrictions as set forth in subparagraphs (a)
and (c) of the Commercial Computer Software - Restricted
Rights clause in FAR 52.227-19.
Gaussian, Inc.
340 Quinnipiac St., Bldg. 40, Wallingford CT 06492
---------------------------------------------------------------
Warning -- This program may not be used in any manner that
competes with the business of Gaussian, Inc. or will provide
assistance to any competitor of Gaussian, Inc. The licensee
of this program is prohibited from giving any competitor of
Gaussian, Inc. access to this program. By using this program,
the user acknowledges that Gaussian, Inc. is engaged in the
business of creating and licensing software in the field of
computational chemistry and represents and warrants to the
licensee that it is not a competitor of Gaussian, Inc. and that
it will not use this program in any manner prohibited above.
---------------------------------------------------------------
Cite this work as:
Gaussian 09, Revision A.02,
M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria,
M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci,
G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian,
A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada,
M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima,
Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr.,
J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers,
K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand,
K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi,
M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross,
V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann,
O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski,
R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth,
P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels,
O. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski,
and D. J. Fox, Gaussian, Inc., Wallingford CT, 2009.
******************************************
Gaussian 09: EM64L-G09RevA.02 11-Jun-2009
24-Feb-2015
******************************************
%chk=h-h-endiin-yyy-1b2-f01a
%mem=5000MB
%nprocshared=8
Will use up to 8 processors via shared memory.
----------------------------------------------------------------------
#p Freq 6-31g* rb2plypd=fc temperature=298.15 pressure=1.000 scale=1.0
00
----------------------------------------------------------------------
1/10=4,30=1,38=1,111=298150,112=1000,113=1000000/1,3;
2/12=2,17=6,18=5,40=1/2;
3/5=1,6=6,7=1,11=1,16=1,25=1,30=1,71=2,74=-49,116=1/1,2,3;
4//1;
5/5=2,38=5,98=1/2;
8/6=3,8=1,10=2,19=11,30=-1/1;
9/15=3,16=-3/6;
11/6=1,8=1,15=11,17=12,24=-1,27=1,28=-2,29=300,32=6,42=3/1,2,10;
10/6=2,21=1/2;
8/6=4,8=1,10=2,19=11,30=-1/11,4;
10/5=1,20=4/2;
11/12=2,14=11,16=1,17=2,28=-2,42=3/2,10,12;
6/7=2,8=2,9=2,10=2/1;
7/8=1,10=1,12=2,25=1,44=2/1,2,3,16;
1/10=4,30=1/3;
99//99;
Leave Link 1 at Tue Feb 24 16:13:31 2015, MaxMem= 655360000 cpu: 0.4
(Enter /opt/g09/l101.exe)
---
xxx
---
Symbolic Z-matrix:
Charge = 0 Multiplicity = 1
C -1.21376 -1.00614 0.0001
C -1.21361 1.00627 -0.00005
C 1.225 -0.70018 0.00003
H 2.1811 -1.21065 0.00006
C 1.2251 0.70003 -0.00009
H 2.18127 1.21037 -0.00016
C 0.00022 1.37664 -0.0001
C 0.00004 -1.37662 0.00009
H -2.25004 1.28302 -0.00004
H -2.25022 -1.28277 0.00017
NAtoms= 10 NQM= 10 NQMF= 0 NMic= 0 NMicF= 0 NTot= 10.
Isotopes and Nuclear Properties:
(Nuclear quadrupole moments (NQMom) in fm**2, nuclear magnetic moments (NMagM)
in nuclear magnetons)
Atom 1 2 3 4 5 6 7 8 9 10
IAtWgt= 12 12 12 1 12 1 12 12 1 1
AtmWgt= 12.0000000 12.0000000 12.0000000 1.0078250 12.0000000 1.0078250 12.0000000 12.0000000 1.0078250 1.0078250
NucSpn= 0 0 0 1 0 1 0 0 1 1
AtZEff= 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000
NQMom= 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000
NMagM= 0.0000000 0.0000000 0.0000000 2.7928460 0.0000000 2.7928460 0.0000000 0.0000000 2.7928460 2.7928460
Leave Link 101 at Tue Feb 24 16:13:31 2015, MaxMem= 655360000 cpu: 0.5
(Enter /opt/g09/l103.exe)
GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad
Berny optimization.
Initialization pass.
Trust Radius=3.00D-01 FncErr=1.00D-07 GrdErr=1.00D-07
Number of steps in this run= 2 maximum allowed number of steps= 2.
GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad
Leave Link 103 at Tue Feb 24 16:13:31 2015, MaxMem= 655360000 cpu: 0.1
(Enter /opt/g09/l202.exe)
Input orientation:
---------------------------------------------------------------------
Center Atomic Atomic Coordinates (Angstroms)
Number Number Type X Y Z
---------------------------------------------------------------------
1 6 0 -1.213762 -1.006139 0.000099
2 6 0 -1.213614 1.006273 -0.000046
3 6 0 1.225004 -0.700180 0.000034
4 1 0 2.181104 -1.210654 0.000061
5 6 0 1.225098 0.700031 -0.000085
6 1 0 2.181270 1.210371 -0.000160
7 6 0 0.000220 1.376638 -0.000096
8 6 0 0.000035 -1.376618 0.000088
9 1 0 -2.250042 1.283017 -0.000038
10 1 0 -2.250220 -1.282767 0.000174
---------------------------------------------------------------------
Distance matrix (angstroms):
1 2 3 4 5
1 C 0.000000
2 C 2.012412 0.000000
3 C 2.457883 2.976380 0.000000
4 H 3.401021 4.054488 1.083841 0.000000
5 C 2.976416 2.457865 1.400211 2.136508 0.000000
6 H 4.054523 3.401014 2.136504 2.421025 1.083841
7 C 2.674206 1.269080 2.411072 3.383834 1.399330
8 C 1.269078 2.674157 1.399327 2.187374 2.411068
9 H 2.512790 1.072740 4.001127 5.084629 3.523701
10 H 1.072739 2.512818 3.523718 4.431911 4.001165
6 7 8 9 10
6 H 0.000000
7 C 2.187378 0.000000
8 C 3.383829 2.753256 0.000000
9 H 4.431907 2.252209 3.483749 0.000000
10 H 5.084667 3.483808 2.252211 2.565784 0.000000
Stoichiometry C6H4
Framework group C1[X(C6H4)]
Deg. of freedom 24
Full point group C1 NOp 1
Largest Abelian subgroup C1 NOp 1
Largest concise Abelian subgroup C1 NOp 1
Standard orientation:
---------------------------------------------------------------------
Center Atomic Atomic Coordinates (Angstroms)
Number Number Type X Y Z
---------------------------------------------------------------------
1 6 0 1.213761 1.006140 0.000099
2 6 0 1.213615 -1.006272 -0.000046
3 6 0 -1.225004 0.700179 0.000034
4 1 0 -2.181105 1.210653 0.000061
5 6 0 -1.225098 -0.700032 -0.000085
6 1 0 -2.181269 -1.210372 -0.000160
7 6 0 -0.000219 -1.376638 -0.000096
8 6 0 -0.000036 1.376618 0.000088
9 1 0 2.250043 -1.283016 -0.000038
10 1 0 2.250219 1.282768 0.000174
---------------------------------------------------------------------
Rotational constants (GHZ): 5.7549853 5.5435210 2.8236371
Leave Link 202 at Tue Feb 24 16:13:31 2015, MaxMem= 655360000 cpu: 0.1
(Enter /opt/g09/l301.exe)
Standard basis: 6-31G(d) (6D, 7F)
Ernie: Thresh= 0.10000D-02 Tol= 0.10000D-05 Strict=F.
There are 98 symmetry adapted basis functions of A symmetry.
Integral buffers will be 131072 words long.
Raffenetti 1 integral format.
Two-electron integral symmetry is turned on.
98 basis functions, 184 primitive gaussians, 98 cartesian basis functions
20 alpha electrons 20 beta electrons
nuclear repulsion energy 179.9878260278 Hartrees.
IExCor= 419 DFT=T Ex+Corr=B2PLYPD ExCW=0 ScaHFX= 0.530000
ScaDFX= 0.470000 0.470000 0.730000 0.730000 ScalE2= 0.270000 0.270000
IRadAn= 0 IRanWt= -1 IRanGd= 0 ICorTp=0
NAtoms= 10 NActive= 10 NUniq= 10 SFac= 7.50D-01 NAtFMM= 80 NAOKFM=F Big=F
R6Disp: Dispersion energy = -0.0034764016 Hartrees.
Nuclear repulsion after empirical dispersion term = 179.9843496261 Hartrees.
Leave Link 301 at Tue Feb 24 16:13:31 2015, MaxMem= 655360000 cpu: 0.4
(Enter /opt/g09/l302.exe)
NPDir=0 NMtPBC= 1 NCelOv= 1 NCel= 1 NClECP= 1 NCelD= 1
NCelK= 1 NCelE2= 1 NClLst= 1 CellRange= 0.0.
One-electron integrals computed using PRISM.
NBasis= 98 RedAO= T NBF= 98
NBsUse= 98 1.00D-06 NBFU= 98
Precomputing XC quadrature grid using
IXCGrd= 2 IRadAn= 0 IRanWt= -1 IRanGd= 0 AccXCQ= 1.00D-10.
NRdTot= 618 NPtTot= 78612 NUsed= 83081 NTot= 83113
NSgBfM= 98 98 98 98 98 NAtAll= 10 10.
Leave Link 302 at Tue Feb 24 16:13:32 2015, MaxMem= 655360000 cpu: 3.0
(Enter /opt/g09/l303.exe)
DipDrv: MaxL=1.
Leave Link 303 at Tue Feb 24 16:13:32 2015, MaxMem= 655360000 cpu: 0.6
(Enter /opt/g09/l401.exe)
Harris functional with IExCor= 419 diagonalized for initial guess.
ExpMin= 1.61D-01 ExpMax= 3.05D+03 ExpMxC= 4.57D+02 IAcc=1 IRadAn= 1 AccDes= 0.00D+00
HarFok: IExCor= 419 AccDes= 0.00D+00 IRadAn= 1 IDoV= 1
ScaDFX= 1.000000 1.000000 1.000000 1.000000
FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 0
NFxFlg= 0 DoJE=T BraDBF=F KetDBF=T FulRan=T
Omega= 0.000000 0.000000 1.000000 0.000000 0.000000 ICntrl= 500 IOpCl= 0
NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
I1Cent= 4 NGrid= 0.
Petite list used in FoFCou.
Harris En= -230.889992895829
Initial guess orbital symmetries:
Occupied (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A)
Virtual (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A)
The electronic state of the initial guess is 1-A.
Leave Link 401 at Tue Feb 24 16:13:34 2015, MaxMem= 655360000 cpu: 5.3
(Enter /opt/g09/l502.exe)
Closed shell SCF:
Requested convergence on RMS density matrix=1.00D-08 within 128 cycles.
Requested convergence on MAX density matrix=1.00D-06.
Requested convergence on energy=1.00D-06.
No special actions if energy rises.
Using DIIS extrapolation, IDIIS= 1040.
Integral symmetry usage will be decided dynamically.
82978 words used for storage of precomputed grid.
Keep R1 ints in memory in canonical form, NReq=12817672.
IEnd= 131458 IEndB= 131458 NGot= 655360000 MDV= 643486331
LenX= 643486331 LenY= 643476286
Symmetry not used in FoFDir.
MinBra= 0 MaxBra= 2 Meth= 1.
IRaf= 0 NMat= 1 IRICut= 1 DoRegI=T DoRafI=F ISym2E= 0 JSym2E=0.
Integral accuracy reduced to 1.0D-05 until final iterations.
Cycle 1 Pass 0 IDiag 1:
E= -230.140026087990
DIIS: error= 4.99D-02 at cycle 1 NSaved= 1.
NSaved= 1 IEnMin= 1 EnMin= -230.140026087990 IErMin= 1 ErrMin= 4.99D-02
ErrMax= 4.99D-02 EMaxC= 1.00D-01 BMatC= 1.56D-01 BMatP= 1.56D-01
IDIUse=3 WtCom= 5.01D-01 WtEn= 4.99D-01
Coeff-Com: 0.100D+01
Coeff-En: 0.100D+01
Coeff: 0.100D+01
Gap= 0.229 Goal= None Shift= 0.000
GapD= 0.229 DampG=1.000 DampE=0.500 DampFc=0.5000 IDamp=-1.
Damping current iteration by 5.00D-01
RMSDP=8.24D-03 MaxDP=9.04D-02 OVMax= 1.31D-01
Cycle 2 Pass 0 IDiag 1:
E= -230.228048272224 Delta-E= -0.088022184234 Rises=F Damp=T
DIIS: error= 1.47D-02 at cycle 2 NSaved= 2.
NSaved= 2 IEnMin= 2 EnMin= -230.228048272224 IErMin= 2 ErrMin= 1.47D-02
ErrMax= 1.47D-02 EMaxC= 1.00D-01 BMatC= 1.74D-02 BMatP= 1.56D-01
IDIUse=3 WtCom= 8.53D-01 WtEn= 1.47D-01
Coeff-Com: -0.275D+00 0.127D+01
Coeff-En: 0.000D+00 0.100D+01
Coeff: -0.234D+00 0.123D+01
Gap= 0.244 Goal= None Shift= 0.000
RMSDP=2.20D-03 MaxDP=2.91D-02 DE=-8.80D-02 OVMax= 6.81D-02
Cycle 3 Pass 0 IDiag 1:
E= -230.299236107902 Delta-E= -0.071187835677 Rises=F Damp=F
DIIS: error= 9.52D-03 at cycle 3 NSaved= 3.
NSaved= 3 IEnMin= 3 EnMin= -230.299236107902 IErMin= 3 ErrMin= 9.52D-03
ErrMax= 9.52D-03 EMaxC= 1.00D-01 BMatC= 5.75D-03 BMatP= 1.74D-02
IDIUse=3 WtCom= 9.05D-01 WtEn= 9.52D-02
Coeff-Com: -0.152D+00 0.529D+00 0.623D+00
Coeff-En: 0.000D+00 0.000D+00 0.100D+01
Coeff: -0.138D+00 0.479D+00 0.659D+00
Gap= 0.237 Goal= None Shift= 0.000
RMSDP=1.13D-03 MaxDP=1.96D-02 DE=-7.12D-02 OVMax= 4.86D-02
Cycle 4 Pass 0 IDiag 1:
E= -230.301442966175 Delta-E= -0.002206858274 Rises=F Damp=F
DIIS: error= 6.76D-03 at cycle 4 NSaved= 4.
NSaved= 4 IEnMin= 4 EnMin= -230.301442966175 IErMin= 4 ErrMin= 6.76D-03
ErrMax= 6.76D-03 EMaxC= 1.00D-01 BMatC= 3.76D-03 BMatP= 5.75D-03
IDIUse=3 WtCom= 9.32D-01 WtEn= 6.76D-02
Coeff-Com: -0.342D-01 0.646D-01 0.453D+00 0.517D+00
Coeff-En: 0.000D+00 0.000D+00 0.413D+00 0.587D+00
Coeff: -0.319D-01 0.602D-01 0.450D+00 0.521D+00
Gap= 0.239 Goal= None Shift= 0.000
RMSDP=5.33D-04 MaxDP=8.83D-03 DE=-2.21D-03 OVMax= 2.19D-02
Cycle 5 Pass 0 IDiag 1:
E= -230.305435278990 Delta-E= -0.003992312815 Rises=F Damp=F
DIIS: error= 5.53D-04 at cycle 5 NSaved= 5.
NSaved= 5 IEnMin= 5 EnMin= -230.305435278990 IErMin= 5 ErrMin= 5.53D-04
ErrMax= 5.53D-04 EMaxC= 1.00D-01 BMatC= 1.26D-05 BMatP= 3.76D-03
IDIUse=3 WtCom= 9.94D-01 WtEn= 5.53D-03
Coeff-Com: -0.179D-02-0.386D-02 0.797D-01 0.119D+00 0.806D+00
Coeff-En: 0.000D+00 0.000D+00 0.000D+00 0.000D+00 0.100D+01
Coeff: -0.178D-02-0.384D-02 0.792D-01 0.119D+00 0.808D+00
Gap= 0.239 Goal= None Shift= 0.000
RMSDP=5.65D-05 MaxDP=6.04D-04 DE=-3.99D-03 OVMax= 1.68D-03
Cycle 6 Pass 0 IDiag 1:
E= -230.305452244241 Delta-E= -0.000016965251 Rises=F Damp=F
DIIS: error= 1.31D-04 at cycle 6 NSaved= 6.
NSaved= 6 IEnMin= 6 EnMin= -230.305452244241 IErMin= 6 ErrMin= 1.31D-04
ErrMax= 1.31D-04 EMaxC= 1.00D-01 BMatC= 8.99D-07 BMatP= 1.26D-05
IDIUse=3 WtCom= 9.99D-01 WtEn= 1.31D-03
Coeff-Com: 0.141D-02-0.356D-02-0.928D-02-0.102D-01 0.676D-01 0.954D+00
Coeff-En: 0.000D+00 0.000D+00 0.000D+00 0.000D+00 0.000D+00 0.100D+01
Coeff: 0.141D-02-0.355D-02-0.927D-02-0.102D-01 0.675D-01 0.954D+00
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=2.11D-05 MaxDP=2.60D-04 DE=-1.70D-05 OVMax= 1.05D-03
Cycle 7 Pass 0 IDiag 1:
E= -230.305454771192 Delta-E= -0.000002526951 Rises=F Damp=F
DIIS: error= 8.18D-05 at cycle 7 NSaved= 7.
NSaved= 7 IEnMin= 7 EnMin= -230.305454771192 IErMin= 7 ErrMin= 8.18D-05
ErrMax= 8.18D-05 EMaxC= 1.00D-01 BMatC= 3.69D-07 BMatP= 8.99D-07
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.884D-03-0.781D-03-0.174D-01-0.259D-01-0.140D+00 0.412D+00
Coeff-Com: 0.771D+00
Coeff: 0.884D-03-0.781D-03-0.174D-01-0.259D-01-0.140D+00 0.412D+00
Coeff: 0.771D+00
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=9.22D-06 MaxDP=1.46D-04 DE=-2.53D-06 OVMax= 5.11D-04
Initial convergence to 1.0D-05 achieved. Increase integral accuracy.
Cycle 8 Pass 1 IDiag 1:
E= -230.305451138602 Delta-E= 0.000003632590 Rises=F Damp=F
DIIS: error= 2.22D-05 at cycle 1 NSaved= 1.
NSaved= 1 IEnMin= 1 EnMin= -230.305451138602 IErMin= 1 ErrMin= 2.22D-05
ErrMax= 2.22D-05 EMaxC= 1.00D-01 BMatC= 1.89D-08 BMatP= 1.89D-08
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.100D+01
Coeff: 0.100D+01
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=9.22D-06 MaxDP=1.46D-04 DE= 3.63D-06 OVMax= 1.80D-04
Cycle 9 Pass 1 IDiag 1:
E= -230.305451194122 Delta-E= -0.000000055520 Rises=F Damp=F
DIIS: error= 1.26D-05 at cycle 2 NSaved= 2.
NSaved= 2 IEnMin= 2 EnMin= -230.305451194122 IErMin= 2 ErrMin= 1.26D-05
ErrMax= 1.26D-05 EMaxC= 1.00D-01 BMatC= 6.96D-09 BMatP= 1.89D-08
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.233D+00 0.767D+00
Coeff: 0.233D+00 0.767D+00
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=1.66D-06 MaxDP=2.88D-05 DE=-5.55D-08 OVMax= 8.77D-05
Cycle 10 Pass 1 IDiag 1:
E= -230.305451200402 Delta-E= -0.000000006281 Rises=F Damp=F
DIIS: error= 1.44D-05 at cycle 3 NSaved= 3.
NSaved= 3 IEnMin= 3 EnMin= -230.305451200402 IErMin= 2 ErrMin= 1.26D-05
ErrMax= 1.44D-05 EMaxC= 1.00D-01 BMatC= 7.71D-09 BMatP= 6.96D-09
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: -0.156D+00 0.577D+00 0.579D+00
Coeff: -0.156D+00 0.577D+00 0.579D+00
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=9.28D-07 MaxDP=2.42D-05 DE=-6.28D-09 OVMax= 6.94D-05
Cycle 11 Pass 1 IDiag 1:
E= -230.305451211629 Delta-E= -0.000000011227 Rises=F Damp=F
DIIS: error= 2.62D-06 at cycle 4 NSaved= 4.
NSaved= 4 IEnMin= 4 EnMin= -230.305451211629 IErMin= 4 ErrMin= 2.62D-06
ErrMax= 2.62D-06 EMaxC= 1.00D-01 BMatC= 2.98D-10 BMatP= 6.96D-09
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: -0.885D-01 0.664D-01 0.158D+00 0.865D+00
Coeff: -0.885D-01 0.664D-01 0.158D+00 0.865D+00
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=4.04D-07 MaxDP=7.03D-06 DE=-1.12D-08 OVMax= 1.98D-05
Cycle 12 Pass 1 IDiag 1:
E= -230.305451212541 Delta-E= -0.000000000912 Rises=F Damp=F
DIIS: error= 9.74D-07 at cycle 5 NSaved= 5.
NSaved= 5 IEnMin= 5 EnMin= -230.305451212541 IErMin= 5 ErrMin= 9.74D-07
ErrMax= 9.74D-07 EMaxC= 1.00D-01 BMatC= 6.07D-11 BMatP= 2.98D-10
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.297D-02-0.112D+00-0.751D-01 0.307D+00 0.877D+00
Coeff: 0.297D-02-0.112D+00-0.751D-01 0.307D+00 0.877D+00
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=1.92D-07 MaxDP=3.15D-06 DE=-9.12D-10 OVMax= 1.01D-05
Cycle 13 Pass 1 IDiag 1:
E= -230.305451212687 Delta-E= -0.000000000146 Rises=F Damp=F
DIIS: error= 1.35D-07 at cycle 6 NSaved= 6.
NSaved= 6 IEnMin= 6 EnMin= -230.305451212687 IErMin= 6 ErrMin= 1.35D-07
ErrMax= 1.35D-07 EMaxC= 1.00D-01 BMatC= 2.17D-12 BMatP= 6.07D-11
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.682D-02-0.283D-01-0.225D-01 0.137D-01 0.221D+00 0.809D+00
Coeff: 0.682D-02-0.283D-01-0.225D-01 0.137D-01 0.221D+00 0.809D+00
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=2.06D-08 MaxDP=3.80D-07 DE=-1.46D-10 OVMax= 8.84D-07
Cycle 14 Pass 1 IDiag 1:
E= -230.305451212689 Delta-E= -0.000000000002 Rises=F Damp=F
DIIS: error= 1.03D-07 at cycle 7 NSaved= 7.
NSaved= 7 IEnMin= 7 EnMin= -230.305451212689 IErMin= 7 ErrMin= 1.03D-07
ErrMax= 1.03D-07 EMaxC= 1.00D-01 BMatC= 4.71D-13 BMatP= 2.17D-12
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.339D-02-0.116D-01-0.923D-02-0.274D-02 0.909D-01 0.432D+00
Coeff-Com: 0.497D+00
Coeff: 0.339D-02-0.116D-01-0.923D-02-0.274D-02 0.909D-01 0.432D+00
Coeff: 0.497D+00
Gap= 0.240 Goal= None Shift= 0.000
RMSDP=9.16D-09 MaxDP=1.93D-07 DE=-2.33D-12 OVMax= 5.12D-07
SCF Done: E(RB2PLYPD) = -230.305451213 A.U. after 14 cycles
Convg = 0.9160D-08 -V/T = 2.0071
KE= 2.286791024818D+02 PE=-8.941394081730D+02 EE= 2.551705048523D+02
Leave Link 502 at Tue Feb 24 16:13:38 2015, MaxMem= 655360000 cpu: 27.0
(Enter /opt/g09/l801.exe)
ExpMin= 1.61D-01 ExpMax= 3.05D+03 ExpMxC= 4.57D+02 IAcc=1 IRadAn= 1 AccDes= 0.00D+00
HarFok: IExCor= 205 AccDes= 0.00D+00 IRadAn= 1 IDoV=-2
ScaDFX= 1.000000 1.000000 1.000000 1.000000
Largest valence mixing into a core orbital is 1.17D-04
Largest core mixing into a valence orbital is 2.86D-05
Range of M.O.s used for correlation: 7 98
NBasis= 98 NAE= 20 NBE= 20 NFC= 6 NFV= 0
NROrb= 92 NOA= 14 NOB= 14 NVA= 78 NVB= 78
Leave Link 801 at Tue Feb 24 16:13:38 2015, MaxMem= 655360000 cpu: 1.1
(Enter /opt/g09/l906.exe)
DoSCS=T DFT=T ScalE2(SS,OS)= 0.270000 0.270000
Frozen-core derivative calculation, NFC= 6 NFV= 0.
FulOut=F Deriv=T AODrv=T NAtomX= 10
MMem= 0 MDisk= 14 MDiskD= 14
W3Min= 192080 MinDsk= 613843 NBas6D= 98
NBas2D= 5013 NTT= 4851 LW2= 3000000
MDV= 655235335 MDiskM= 92578 NBas2p= 5010
Disk-based method using ON**2 memory for 14 occupieds at a time.
Permanent disk used for amplitudes= 3004170 words.
Estimated scratch disk usage= 26617100 words.
IMap= 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Actual scratch disk usage= 24300300 words.
JobTyp=1 Pass 1: I= 7 to 20 NPSUse= 8 ParTrn=T ParDer=T DoDerP=T.
(rs|ai) integrals will be sorted in core.
Spin components of T(2) and E(2):
alpha-alpha T2 = 0.8522199250D-01 E2= -0.3787090367D-01
alpha-beta T2 = 0.4480565590D+00 E2= -0.2012592452D+00
beta-beta T2 = 0.8522199250D-01 E2= -0.3787090367D-01
The integrals were generated 1 times.
E2(B2PLYPD) = -0.2770010526D+00 E(B2PLYPD) = -0.23058245226525D+03
Leave Link 906 at Tue Feb 24 16:13:58 2015, MaxMem= 655360000 cpu: 105.1
(Enter /opt/g09/l1101.exe)
Using compressed Sx but separate Hx and Fx, NAtomX= 10.
Will process 11 centers per pass.
R6Disp: Adding dispersion energy 1st derivatives to the gradient.
Leave Link 1101 at Tue Feb 24 16:13:59 2015, MaxMem= 655360000 cpu: 1.9
(Enter /opt/g09/l1102.exe)
Leave Link 1102 at Tue Feb 24 16:13:59 2015, MaxMem= 655360000 cpu: 0.1
(Enter /opt/g09/l1110.exe)
Forming Gx(P) for the SCF density, NAtomX= 10.
Integral derivatives from FoFDir/FoFCou, PRISM(SPDF).
Do as many integral derivatives as possible in FoFDir.
G2DrvN: MDV= 655359816.
G2DrvN: will do 11 centers at a time, making 1 passes doing MaxLOS=2.
Calling FoFCou, ICntrl= 3107 FMM=F I1Cent= 0 AccDes= 0.00D+00.
FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 0
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
Omega= 0.000000 0.000000 1.000000 0.000000 0.000000 ICntrl= 3107 IOpCl= 0
NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
I1Cent= 0 NGrid= 0.
Symmetry not used in FoFCou.
FoFDir/FoFCou used for L=0 through L=2.
End of G2Drv Frequency-dependent properties file 721 does not exist.
End of G2Drv Frequency-dependent properties file 722 does not exist.
Leave Link 1110 at Tue Feb 24 16:14:07 2015, MaxMem= 655360000 cpu: 41.8
(Enter /opt/g09/l1002.exe)
Minotr: Closed shell wavefunction.
IDoAtm=1111111111
Frozen-core window.
Direct CPHF calculation.
Differentiating once with respect to electric field.
with respect to dipole field.
Differentiating once with respect to nuclear coordinates.
Requested convergence is 1.0D-08 RMS, and 1.0D-07 maximum.
Secondary convergence is 1.0D-12 RMS, and 1.0D-12 maximum.
NewPWx=T KeepS1=T KeepF1=T KeepIn=T MapXYZ=F SortEE=F KeepMc=T.
MDV= 655359896 using IRadAn= 2.
Generate precomputed XC quadrature information.
Keep R1 ints in memory in canonical form, NReq=12591586.
Symmetry not used in FoFDir.
MinBra= 0 MaxBra= 2 Meth= 1.
IRaf= 0 NMat= 1 IRICut= 1 DoRegI=T DoRafI=F ISym2E= 0 JSym2E=0.
Solving linear equations simultaneously, MaxMat= 0.
There are 33 degrees of freedom in the 1st order CPHF. IDoFFX=5.
30 vectors produced by pass 0 Test12= 4.73D-15 3.03D-09 XBig12= 1.07D+02 7.95D+00.
AX will form 30 AO Fock derivatives at one time.
30 vectors produced by pass 1 Test12= 4.73D-15 3.03D-09 XBig12= 2.15D+01 1.96D+00.
30 vectors produced by pass 2 Test12= 4.73D-15 3.03D-09 XBig12= 3.07D-01 1.51D-01.
30 vectors produced by pass 3 Test12= 4.73D-15 3.03D-09 XBig12= 2.11D-03 1.09D-02.
30 vectors produced by pass 4 Test12= 4.73D-15 3.03D-09 XBig12= 9.14D-06 5.25D-04.
30 vectors produced by pass 5 Test12= 4.73D-15 3.03D-09 XBig12= 3.13D-08 3.81D-05.
21 vectors produced by pass 6 Test12= 4.73D-15 3.03D-09 XBig12= 8.33D-11 1.88D-06.
3 vectors produced by pass 7 Test12= 4.73D-15 3.03D-09 XBig12= 2.29D-13 1.42D-07.
1 vectors produced by pass 8 Test12= 4.73D-15 3.03D-09 XBig12= 4.29D-16 3.58D-09.
Inverted reduced A of dimension 205 with in-core refinement.
FullF1: Do perturbations 1 to 33.
Saving first derivative matrices.
End of Minotr Frequency-dependent properties file 721 does not exist.
End of Minotr Frequency-dependent properties file 722 does not exist.
Leave Link 1002 at Tue Feb 24 16:14:21 2015, MaxMem= 655360000 cpu: 67.4
(Enter /opt/g09/l811.exe)
MDV= 655360000.
DoSCS=T DFT=T ScalE2(SS,OS)= 0.270000 0.270000
Form MO integral derivatives with frozen-active canonical formalism.
MOERI=1 MOERIx=1 NAtoms= 10 NAtomX= 10.
Discarding MO integrals.
MO basis two electron integral derivatives will not be stored on disk.
IAlg= 3 DoFC=T DoPWx=T Debug=F.
Frozen-core window: NFC= 6 NFV= 0.
Reordered first order wavefunction length = 4867200
In DefCFB: NBatch= 1 ICI= 20 ICA= 78 LFMax= 39
Large arrays: LIAPS= 59928960 LIARS= 16052400 words.
In StABat: MaxSiz= 15 MinSiz= 8 NAtomB= 7
DoIAMN: NPSUse= 8.
Leave Link 811 at Tue Feb 24 16:14:59 2015, MaxMem= 655360000 cpu: 198.8
(Enter /opt/g09/l804.exe)
Frozen-core window: NFC= 6 NFV= 0.
Closed-shell transformation, MDV= 655360000 ITran=4 ISComp=1.
Semi-Direct transformation.
ModeAB= 2 MOrb= 20 LenV= 655012491
LASXX= 8003395 LTotXX= 8003395 LenRXX= 8003395
LTotAB= 8258670 MaxLAS= 9507960 LenRXY= 9507960
NonZer= 16006790 LenScr= 24772608 LnRSAI= 0
LnScr1= 0 LExtra= 0 Total= 42283963
MaxDsk= -1 SrtSym= F ITran= 4
DoSDTr: NPSUse= 8
JobTyp=0 Pass 1: I= 1 to 20.
(rs|ai) integrals will be sorted in core.
Complete sort for first half transformation.
First half transformation complete.
Begin second half transformation for I= 10.
Begin second half transformation for I= 20.
Begin second half transformation for I= 10.
Begin second half transformation for I= 20.
Complete sort for second half transformation.
Second half transformation complete.
SymMOI: orbitals are not symmetric.
DoSCS=T DFT=T ScalE2(SS,OS)= 0.270000 0.270000
Spin components of T(2) and E(2):
alpha-alpha T2 = 0.8522199250D-01 E2= -0.3787090367D-01
alpha-beta T2 = 0.4480565590D+00 E2= -0.2012592452D+00
beta-beta T2 = 0.8522199250D-01 E2= -0.3787090367D-01
E2(B2PLYPD) = -0.2770010526D+00 E(B2PLYPD) = -0.23058245226525D+03
Leave Link 804 at Tue Feb 24 16:15:06 2015, MaxMem= 655360000 cpu: 43.8
(Enter /opt/g09/l1002.exe)
Minotr: Closed shell wavefunction.
Computing MP2/KS-MP2 derivatives.
Using Z-Vector for PSCF gradient.
Skipping F1 and S1 gradient terms here.
IDoAtm=1111111111
Frozen-core window.
Direct CPHF calculation.
Differentiating once with respect to electric field.
with respect to dipole field.
Differentiating once with respect to nuclear coordinates.
Requested convergence is 1.0D-10 RMS, and 1.0D-09 maximum.
NewPWx=T KeepS1=F KeepF1=F KeepIn=T MapXYZ=F SortEE=F KeepMc=T.
MDV= 655359896 using IRadAn= 0.
Generate precomputed XC quadrature information.
Keep R1 ints in memory in canonical form, NReq=12593896.
Symmetry not used in FoFDir.
MinBra= 0 MaxBra= 2 Meth= 1.
IRaf= 0 NMat= 1 IRICut= 1 DoRegI=T DoRafI=F ISym2E= 0 JSym2E=0.
Solving linear equations separately, MaxMat= 0.
There are 1 degrees of freedom in the 1st order CPHF. IDoFFX=0.
LinEq1: Iter= 0 NonCon= 1 RMS=3.17D-03 Max=6.03D-02
AX will form 1 AO Fock derivatives at one time.
LinEq1: Iter= 1 NonCon= 1 RMS=1.08D-03 Max=1.46D-02
LinEq1: Iter= 2 NonCon= 1 RMS=5.09D-04 Max=1.38D-02
LinEq1: Iter= 3 NonCon= 1 RMS=4.92D-04 Max=1.14D-02
LinEq1: Iter= 4 NonCon= 1 RMS=1.65D-04 Max=1.81D-03
LinEq1: Iter= 5 NonCon= 1 RMS=5.66D-05 Max=8.98D-04
LinEq1: Iter= 6 NonCon= 1 RMS=2.76D-05 Max=5.60D-04
LinEq1: Iter= 7 NonCon= 1 RMS=5.50D-06 Max=8.43D-05
LinEq1: Iter= 8 NonCon= 1 RMS=1.05D-06 Max=1.24D-05
LinEq1: Iter= 9 NonCon= 1 RMS=7.34D-07 Max=1.98D-05
LinEq1: Iter= 10 NonCon= 1 RMS=2.61D-07 Max=1.85D-06
LinEq1: Iter= 11 NonCon= 1 RMS=6.56D-08 Max=1.50D-06
LinEq1: Iter= 12 NonCon= 1 RMS=1.37D-08 Max=2.36D-07
LinEq1: Iter= 13 NonCon= 1 RMS=6.73D-09 Max=1.51D-07
LinEq1: Iter= 14 NonCon= 1 RMS=2.42D-09 Max=2.31D-08
LinEq1: Iter= 15 NonCon= 1 RMS=4.23D-10 Max=5.30D-09
LinEq1: Iter= 16 NonCon= 1 RMS=9.68D-11 Max=1.50D-09
LinEq1: Iter= 17 NonCon= 0 RMS=3.26D-11 Max=4.30D-10
Linear equations converged to 1.000D-10 1.000D-09 after 17 iterations.
End of Minotr Frequency-dependent properties file 721 does not exist.
End of Minotr Frequency-dependent properties file 722 does not exist.
Leave Link 1002 at Tue Feb 24 16:15:16 2015, MaxMem= 655360000 cpu: 57.4
(Enter /opt/g09/l1102.exe)
Use density number 2.
Symmetrizing basis deriv contribution to polar:
IMax=3 JMax=2 DiffMx= 0.00D+00
Leave Link 1102 at Tue Feb 24 16:15:16 2015, MaxMem= 655360000 cpu: 0.6
(Enter /opt/g09/l1110.exe)
Forming Gx(P) for generalized density number 2 NAtomX= 10.
Integral derivatives from FoFDir/FoFCou, PRISM(SPDF).
Do as many integral derivatives as possible in FoFDir.
G2DrvN: MDV= 655359816.
G2DrvN: will do 11 centers at a time, making 1 passes doing MaxLOS=2.
Calling FoFCou, ICntrl= 3107 FMM=F I1Cent= 0 AccDes= 0.00D+00.
FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 0
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
Omega= 0.000000 0.000000 1.000000 0.000000 0.000000 ICntrl= 3107 IOpCl= 0
NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
I1Cent= 0 NGrid= 0.
Symmetry not used in FoFCou.
FoFDir/FoFCou used for L=0 through L=2.
End of G2Drv Frequency-dependent properties file 721 does not exist.
End of G2Drv Frequency-dependent properties file 722 does not exist.
Leave Link 1110 at Tue Feb 24 16:15:25 2015, MaxMem= 655360000 cpu: 45.8
(Enter /opt/g09/l1112.exe)
MP22nd: MDV= 655360000
DoSCS=T DFT=T ScalE2(SS,OS)= 0.270000 0.270000
Generate precomputed XC quadrature information.
This link is doing NAtomX= 10 total of 33 degrees of freedom.
Using ON3 I/O method in MakUI.
Frozen-core window: NFC= 6 NFV= 0.
Using Ix for Sx.
Use MO integrals over full window.
Using OV2 memory method for fx*t*t/D, MaxI= 20 DoOO2=F NP= 8.
R2 and R3 integrals will be kept in memory, NReq= 24357052.
Symmetry not used in FoFDir.
MinBra= 0 MaxBra= 2 Meth= 1.
IRaf= 0 NMat= 1 IRICut= 1 DoRegI=T DoRafI=F ISym2E= 0 JSym2E=0.
DD1Dir will call FoFMem 1 times, MxPair= 990
NAB= 400 NAA= 190 NBB= 0.
Symmetry is being used.
R6Disp: Adding dispersion energy 1st derivatives to the gradient.
Discarding MO integrals.
Leave Link 1112 at Tue Feb 24 16:16:23 2015, MaxMem= 655360000 cpu: 312.3
(Enter /opt/g09/l601.exe)
Copying SCF densities to generalized density rwf, IOpCl= 0 IROHF=0.
**********************************************************************
Population analysis using the SCF density.
**********************************************************************
Orbital symmetries:
Occupied (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A)
Virtual (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
(A) (A) (A) (A) (A) (A)
The electronic state is 1-A.
Alpha occ. eigenvalues -- -10.65781 -10.65702 -10.65456 -10.65451 -10.63151
Alpha occ. eigenvalues -- -10.63148 -0.96109 -0.86081 -0.84040 -0.72191
Alpha occ. eigenvalues -- -0.65720 -0.58021 -0.55059 -0.53634 -0.46816
Alpha occ. eigenvalues -- -0.41671 -0.39819 -0.32062 -0.27203 -0.25854
Alpha virt. eigenvalues -- -0.01887 0.00904 0.11313 0.15495 0.16680
Alpha virt. eigenvalues -- 0.18700 0.20675 0.23754 0.25242 0.35426
Alpha virt. eigenvalues -- 0.40632 0.44000 0.50205 0.55857 0.59117
Alpha virt. eigenvalues -- 0.59335 0.61932 0.67284 0.67744 0.67815
Alpha virt. eigenvalues -- 0.68004 0.71556 0.73187 0.74941 0.77476
Alpha virt. eigenvalues -- 0.77620 0.80516 0.84700 0.90981 0.91284
Alpha virt. eigenvalues -- 0.94915 0.97638 1.00846 1.01776 1.06633
Alpha virt. eigenvalues -- 1.15289 1.18799 1.21166 1.28568 1.35241
Alpha virt. eigenvalues -- 1.40196 1.47845 1.51948 1.54371 1.64790
Alpha virt. eigenvalues -- 1.64873 1.66497 1.69944 1.79400 1.84298
Alpha virt. eigenvalues -- 1.91083 1.97719 1.98740 2.01284 2.08070
Alpha virt. eigenvalues -- 2.12428 2.26622 2.31516 2.34044 2.40417
Alpha virt. eigenvalues -- 2.43930 2.45809 2.59124 2.63363 2.66203
Alpha virt. eigenvalues -- 2.76593 2.81719 2.82659 2.99223 3.10902
Alpha virt. eigenvalues -- 3.20346 3.43081 4.22862 4.30419 4.31301
Alpha virt. eigenvalues -- 4.42021 4.54396 4.79186
Condensed to atoms (all electrons):
1 2 3 4 5 6
1 C 5.042728 0.125551 -0.069369 0.003115 -0.018775 0.000414
2 C 0.125551 5.042724 -0.018777 0.000414 -0.069367 0.003115
3 C -0.069369 -0.018777 4.907134 0.368696 0.569711 -0.038986
4 H 0.003115 0.000414 0.368696 0.506141 -0.038984 -0.004574
5 C -0.018775 -0.069367 0.569711 -0.038984 4.907119 0.368697
6 H 0.000414 0.003115 -0.038986 -0.004574 0.368697 0.506143
7 C -0.034403 0.868571 -0.036821 0.003522 0.512509 -0.030033
8 C 0.868572 -0.034401 0.512507 -0.030033 -0.036818 0.003522
9 H -0.009008 0.348725 0.000340 -0.000001 0.002329 -0.000102
10 H 0.348725 -0.009007 0.002329 -0.000102 0.000340 -0.000001
7 8 9 10
1 C -0.034403 0.868572 -0.009008 0.348725
2 C 0.868571 -0.034401 0.348725 -0.009007
3 C -0.036821 0.512507 0.000340 0.002329
4 H 0.003522 -0.030033 -0.000001 -0.000102
5 C 0.512509 -0.036818 0.002329 0.000340
6 H -0.030033 0.003522 -0.000102 -0.000001
7 C 4.825938 -0.126192 -0.021794 0.001514
8 C -0.126192 4.825920 0.001513 -0.021794
9 H -0.021794 0.001513 0.454867 -0.002179
10 H 0.001514 -0.021794 -0.002179 0.454864
Mulliken atomic charges:
1
1 C -0.257550
2 C -0.257548
3 C -0.196763
4 H 0.191806
5 C -0.196761
6 H 0.191804
7 C 0.037189
8 C 0.037203
9 H 0.225309
10 H 0.225311
Sum of Mulliken atomic charges = 0.00000
Mulliken charges with hydrogens summed into heavy atoms:
1
1 C -0.032239
2 C -0.032239
3 C -0.004957
5 C -0.004957
7 C 0.037189
8 C 0.037203
Sum of Mulliken charges with hydrogens summed into heavy atoms = 0.00000
APT atomic charges:
1
1 C -0.032916
2 C -0.032902
3 C 0.097683
4 H 0.070833
5 C 0.097707
6 H 0.070829
7 C -0.305570
8 C -0.305551
9 H 0.169942
10 H 0.169947
Sum of APT charges= 0.00000
APT Atomic charges with hydrogens summed into heavy atoms:
1
1 C 0.137031
2 C 0.137040
3 C 0.168515
4 H 0.000000
5 C 0.168535
6 H 0.000000
7 C -0.305570
8 C -0.305551
9 H 0.000000
10 H 0.000000
Sum of APT charges= 0.00000
Electronic spatial extent (au): <R**2>= 438.5392
Charge= 0.0000 electrons
Dipole moment (field-independent basis, Debye):
X= 0.4495 Y= 0.0002 Z= 0.0001 Tot= 0.4495
Quadrupole moment (field-independent basis, Debye-Ang):
XX= -23.6358 YY= -37.0740 ZZ= -37.6692
XY= -0.0008 XZ= 0.0004 YZ= 0.0002
Traceless Quadrupole moment (field-independent basis, Debye-Ang):
XX= 9.1572 YY= -4.2810 ZZ= -4.8762
XY= -0.0008 XZ= 0.0004 YZ= 0.0002
Octapole moment (field-independent basis, Debye-Ang**2):
XXX= 8.6992 YYY= 0.0013 ZZZ= 0.0000 XYY= -0.6800
XXY= -0.0003 XXZ= 0.0005 XZZ= -0.6145 YZZ= 0.0001
YYZ= 0.0001 XYZ= 0.0000
Hexadecapole moment (field-independent basis, Debye-Ang**3):
XXXX= -229.8283 YYYY= -305.9995 ZZZZ= -39.7985 XXXY= -0.0004
XXXZ= -0.0005 YYYX= -0.0058 YYYZ= -0.0094 ZZZX= -0.0032
ZZZY= -0.0095 XXYY= -76.6813 XXZZ= -61.4730 YYZZ= -57.0715
XXYZ= -0.0006 YYXZ= -0.0003 ZZXY= -0.0001
N-N= 1.799843496261D+02 E-N=-8.941394100134D+02 KE= 2.286791024818D+02
Exact polarizability: 74.336 0.000 71.847 0.001 0.004 21.151
Approx polarizability: 114.542 0.002 134.322 0.002 0.008 27.320
No NMR shielding tensors so no spin-rotation constants.
Leave Link 601 at Tue Feb 24 16:16:23 2015, MaxMem= 655360000 cpu: 2.4
(Enter /opt/g09/l701.exe)
Compute integral second derivatives.
... and contract with generalized density number 2.
R6Disp: Adding dispersion energy 2nd derivatives to the Hessian.
Leave Link 701 at Tue Feb 24 16:16:24 2015, MaxMem= 655360000 cpu: 1.9
(Enter /opt/g09/l702.exe)
L702 exits ... SP integral derivatives will be done elsewhere.
Leave Link 702 at Tue Feb 24 16:16:24 2015, MaxMem= 655360000 cpu: 0.0
(Enter /opt/g09/l703.exe)
Compute integral second derivatives, UseDBF=F ICtDFT= 0.
Integral derivatives from FoFDir, PRISM(SPDF).
Calling FoFJK, ICntrl= 100127 FMM=F ISym2X=0 I1Cent= 0 IOpClX= 0 NMat=1 NMatS=1 NMatT=0.
FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 800
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
Omega= 0.000000 0.000000 1.000000 0.000000 0.000000 ICntrl= 100127 IOpCl= 0
NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
I1Cent= 0 NGrid= 0.
Symmetry not used in FoFCou.
Leave Link 703 at Tue Feb 24 16:16:42 2015, MaxMem= 655360000 cpu: 98.5
(Enter /opt/g09/l716.exe)
Dipole = 1.63309600D-01 4.73094561D-05 1.80485421D-05
Polarizability= 7.43358194D+01 2.78972706D-04 7.18468450D+01
1.28446258D-03 3.73493916D-03 2.11511532D+01
Full mass-weighted force constant matrix:
Low frequencies --- -544.8235 0.0006 0.0008 0.0009 7.1637 8.2197
Low frequencies --- 12.4465 341.2453 409.6317
****** 1 imaginary frequencies (negative Signs) ******
Diagonal vibrational polarizability:
1.8445966 15.3885863 10.3708254
Harmonic frequencies (cm**-1), IR intensities (KM/Mole), Raman scattering
activities (A**4/AMU), depolarization ratios for plane and unpolarized
incident light, reduced masses (AMU), force constants (mDyne/A),
and normal coordinates:
1 2 3
A A A
Frequencies -- -544.8235 341.2453 409.6317
Red. masses -- 11.2276 3.9313 3.0018
Frc consts -- 1.9636 0.2697 0.2968
IR Inten -- 3.4077 0.0000 2.4696
Atom AN X Y Z X Y Z X Y Z
1 6 0.04 0.67 0.00 0.00 0.00 0.29 0.00 0.00 0.16
2 6 0.04 -0.67 0.00 0.00 0.00 -0.29 0.00 0.00 0.16
3 6 -0.06 -0.05 0.00 0.00 0.00 -0.17 0.00 0.00 0.05
4 1 -0.02 0.04 0.00 0.00 0.00 -0.28 0.00 0.00 0.64
5 6 -0.06 0.05 0.00 0.00 0.00 0.17 0.00 0.00 0.05
6 1 -0.02 -0.04 0.00 0.00 0.00 0.28 0.00 0.00 0.64
7 6 0.01 0.05 0.00 0.00 0.00 0.14 0.00 0.00 -0.25
8 6 0.01 -0.05 0.00 0.00 0.00 -0.14 0.00 0.00 -0.25
9 1 0.16 -0.09 0.00 0.00 0.00 -0.54 0.00 0.00 -0.06
10 1 0.16 0.09 0.00 0.00 0.00 0.54 0.00 0.00 -0.06
4 5 6
A A A
Frequencies -- 411.4672 498.6397 572.2484
Red. masses -- 6.2779 1.2487 4.7871
Frc consts -- 0.6262 0.1829 0.9236
IR Inten -- 62.1583 62.9283 0.0000
Atom AN X Y Z X Y Z X Y Z
1 6 0.26 0.29 0.00 0.00 0.00 -0.06 0.00 0.00 0.05
2 6 -0.26 0.29 0.00 0.00 0.00 -0.06 0.00 0.00 -0.05
3 6 0.12 -0.13 0.00 0.00 0.00 0.07 0.00 0.00 0.32
4 1 0.21 0.03 0.00 0.00 0.00 -0.11 0.00 0.00 0.48
5 6 -0.12 -0.13 0.00 0.00 0.00 0.07 0.00 0.00 -0.32
6 1 -0.21 0.03 0.00 0.00 0.00 -0.11 0.00 0.00 -0.48
7 6 -0.14 -0.20 0.00 0.00 0.00 -0.06 0.00 0.00 0.26
8 6 0.14 -0.20 0.00 0.00 0.00 -0.06 0.00 0.00 -0.26
9 1 -0.22 0.41 0.00 0.00 0.00 0.69 0.00 0.00 -0.32
10 1 0.22 0.41 0.00 0.00 0.00 0.69 0.00 0.00 0.32
7 8 9
A A A
Frequencies -- 622.8724 627.0015 718.7777
Red. masses -- 9.1425 1.2765 1.4529
Frc consts -- 2.0898 0.2957 0.4422
IR Inten -- 4.9493 0.0000 60.7398
Atom AN X Y Z X Y Z X Y Z
1 6 0.15 -0.08 0.00 0.00 0.00 -0.10 0.00 0.00 -0.05
2 6 0.15 0.08 0.00 0.00 0.00 0.10 0.00 0.00 -0.05
3 6 -0.22 -0.02 0.00 0.00 0.00 -0.02 0.00 0.00 -0.11
4 1 -0.04 0.32 0.00 0.00 0.00 0.03 0.00 0.00 0.65
5 6 -0.22 0.02 0.00 0.00 0.00 0.02 0.00 0.00 -0.11
6 1 -0.04 -0.32 0.00 0.00 0.00 -0.03 0.00 0.00 0.65
7 6 0.06 0.54 0.00 0.00 0.00 -0.03 0.00 0.00 0.08
8 6 0.06 -0.54 0.00 0.00 0.00 0.03 0.00 0.00 0.08
9 1 0.09 -0.13 0.00 0.00 0.00 -0.70 0.00 0.00 0.25
10 1 0.09 0.13 0.00 0.00 0.00 0.70 0.00 0.00 0.25
10 11 12
A A A
Frequencies -- 737.2396 847.8142 920.0052
Red. masses -- 6.2010 1.0314 1.1911
Frc consts -- 1.9858 0.4368 0.5940
IR Inten -- 99.6741 24.6309 0.0000
Atom AN X Y Z X Y Z X Y Z
1 6 0.00 0.01 0.00 -0.02 0.00 0.00 0.00 0.00 0.01
2 6 0.00 0.01 0.00 -0.02 0.00 0.00 0.00 0.00 -0.01
3 6 -0.25 0.26 0.00 -0.01 -0.01 0.00 0.00 0.00 -0.09
4 1 -0.24 0.27 0.00 0.00 0.03 0.00 0.00 0.00 0.70
5 6 0.25 0.26 0.00 -0.01 0.01 0.00 0.00 0.00 0.09
6 1 0.24 0.27 0.00 0.00 -0.03 0.00 0.00 0.00 -0.70
7 6 0.05 -0.32 0.00 0.02 0.01 0.00 0.00 0.00 0.01
8 6 -0.05 -0.32 0.00 0.02 -0.01 0.00 0.00 0.00 -0.01
9 1 0.10 0.35 0.00 0.15 0.69 0.00 0.00 0.00 0.05
10 1 -0.10 0.35 0.00 0.15 -0.69 0.00 0.00 0.00 -0.05
13 14 15
A A A
Frequencies -- 956.9668 1037.8994 1116.1885
Red. masses -- 1.2210 5.0612 2.1222
Frc consts -- 0.6588 3.2123 1.5578
IR Inten -- 10.6269 0.4522 11.4602
Atom AN X Y Z X Y Z X Y Z
1 6 0.01 0.08 0.00 -0.17 0.02 0.00 -0.13 0.05 0.00
2 6 -0.01 0.08 0.00 -0.17 -0.02 0.00 0.13 0.05 0.00
3 6 -0.06 0.00 0.00 0.28 -0.17 0.00 0.14 0.02 0.00
4 1 -0.10 -0.07 0.00 0.13 -0.52 0.00 0.39 0.49 0.00
5 6 0.06 0.00 0.00 0.28 0.17 0.00 -0.14 0.02 0.00
6 1 0.10 -0.07 0.00 0.13 0.52 0.00 -0.39 0.49 0.00
7 6 0.00 -0.02 0.00 -0.10 0.20 0.00 0.07 -0.09 0.00
8 6 0.00 -0.02 0.00 -0.10 -0.20 0.00 -0.07 -0.09 0.00
9 1 -0.20 -0.66 0.00 -0.18 0.05 0.00 0.08 -0.23 0.00
10 1 0.20 -0.66 0.00 -0.18 -0.05 0.00 -0.08 -0.23 0.00
16 17 18
A A A
Frequencies -- 1193.5442 1406.0698 1406.3707
Red. masses -- 1.2512 4.7940 1.7660
Frc consts -- 1.0501 5.5842 2.0579
IR Inten -- 6.4433 1.3961 0.1165
Atom AN X Y Z X Y Z X Y Z
1 6 -0.06 0.01 0.00 -0.02 0.04 0.00 0.05 -0.02 0.00
2 6 -0.06 -0.01 0.00 -0.02 -0.04 0.00 -0.05 -0.02 0.00
3 6 0.06 0.06 0.00 0.09 0.39 0.00 -0.14 -0.10 0.00
4 1 0.35 0.60 0.00 -0.36 -0.44 0.00 0.24 0.63 0.00
5 6 0.06 -0.06 0.00 0.09 -0.39 0.00 0.14 -0.10 0.00
6 1 0.35 -0.60 0.00 -0.36 0.43 0.00 -0.24 0.64 0.00
7 6 -0.02 0.02 0.00 -0.04 0.09 0.00 0.00 0.06 0.00
8 6 -0.02 -0.02 0.00 -0.04 -0.09 0.00 0.00 0.06 0.00
9 1 -0.06 0.00 0.00 0.00 0.08 0.00 -0.05 0.03 0.00
10 1 -0.06 0.00 0.00 0.00 -0.08 0.00 0.05 0.03 0.00
19 20 21
A A A
Frequencies -- 1778.1936 1909.7094 3238.0965
Red. masses -- 6.4776 7.7045 1.0863
Frc consts -- 12.0677 16.5551 6.7110
IR Inten -- 2.7226 0.7127 0.0921
Atom AN X Y Z X Y Z X Y Z
1 6 0.29 -0.01 0.00 0.30 -0.08 0.00 0.00 0.00 0.00
2 6 0.29 0.01 0.00 -0.30 -0.08 0.00 0.00 0.00 0.00
3 6 0.06 -0.02 0.00 0.10 0.06 0.00 0.05 -0.03 0.00
4 1 0.13 0.07 0.00 0.06 -0.02 0.00 -0.62 0.33 0.00
5 6 0.06 0.02 0.00 -0.10 0.06 0.00 -0.05 -0.03 0.00
6 1 0.13 -0.07 0.00 -0.06 -0.02 0.00 0.62 0.33 0.00
7 6 -0.40 -0.02 0.00 0.44 0.02 0.00 0.00 0.00 0.00
8 6 -0.40 0.02 0.00 -0.44 0.02 0.00 0.00 0.00 0.00
9 1 0.46 0.14 0.00 -0.44 0.01 0.00 -0.01 0.00 0.00
10 1 0.46 -0.14 0.00 0.44 0.01 0.00 0.01 0.00 0.00
22 23 24
A A A
Frequencies -- 3253.4738 3403.8510 3409.6395
Red. masses -- 1.0943 1.1181 1.1163
Frc consts -- 6.8248 7.6329 7.6465
IR Inten -- 3.1999 2.7694 37.5181
Atom AN X Y Z X Y Z X Y Z
1 6 0.00 0.00 0.00 0.07 0.01 0.00 0.07 0.01 0.00
2 6 0.00 0.00 0.00 -0.07 0.01 0.00 0.07 -0.01 0.00
3 6 -0.05 0.03 0.00 0.00 0.00 0.00 0.00 0.00 0.00
4 1 0.62 -0.33 0.00 0.00 0.00 0.00 0.00 0.00 0.00
5 6 -0.05 -0.03 0.00 0.00 0.00 0.00 0.00 0.00 0.00
6 1 0.62 0.33 0.00 0.00 0.00 0.00 0.00 0.00 0.00
7 6 0.00 0.00 0.00 0.01 0.00 0.00 -0.01 0.00 0.00
8 6 0.00 0.00 0.00 -0.01 0.00 0.00 -0.01 0.00 0.00
9 1 0.00 0.00 0.00 0.68 -0.18 0.00 -0.68 0.18 0.00
10 1 0.00 0.00 0.00 -0.68 -0.17 0.00 -0.68 -0.18 0.00
-------------------
- Thermochemistry -
-------------------
Temperature 298.150 Kelvin. Pressure 1.00000 Atm.
Atom 1 has atomic number 6 and mass 12.00000
Atom 2 has atomic number 6 and mass 12.00000
Atom 3 has atomic number 6 and mass 12.00000
Atom 4 has atomic number 1 and mass 1.00783
Atom 5 has atomic number 6 and mass 12.00000
Atom 6 has atomic number 1 and mass 1.00783
Atom 7 has atomic number 6 and mass 12.00000
Atom 8 has atomic number 6 and mass 12.00000
Atom 9 has atomic number 1 and mass 1.00783
Atom 10 has atomic number 1 and mass 1.00783
Molecular mass: 76.03130 amu.
Principal axes and moments of inertia in atomic units:
1 2 3
Eigenvalues -- 313.59615 325.55865 639.15479
X 1.00000 -0.00022 -0.00002
Y 0.00022 1.00000 -0.00007
Z 0.00002 0.00007 1.00000
This molecule is an asymmetric top.
Rotational symmetry number 1.
Rotational temperatures (Kelvin) 0.27620 0.26605 0.13551
Rotational constants (GHZ): 5.75499 5.54352 2.82364
1 imaginary frequencies ignored.
Zero-point vibrational energy 184326.3 (Joules/Mol)
44.05504 (Kcal/Mol)
Warning -- explicit consideration of 5 degrees of freedom as
vibrations may cause significant error
Vibrational temperatures: 490.98 589.37 592.01 717.43 823.34
(Kelvin) 896.17 902.11 1034.16 1060.72 1219.81
1323.68 1376.86 1493.30 1605.94 1717.24
2023.02 2023.45 2558.42 2747.64 4658.89
4681.02 4897.38 4905.70
Zero-point correction= 0.070206 (Hartree/Particle)
Thermal correction to Energy= 0.075155
Thermal correction to Enthalpy= 0.076099
Thermal correction to Gibbs Free Energy= 0.042460
Sum of electronic and zero-point Energies= -230.512246
Sum of electronic and thermal Energies= -230.507297
Sum of electronic and thermal Enthalpies= -230.506353
Sum of electronic and thermal Free Energies= -230.539993
E (Thermal) CV S
KCal/Mol Cal/Mol-Kelvin Cal/Mol-Kelvin
Total 47.161 18.846 70.801
Electronic 0.000 0.000 0.000
Translational 0.889 2.981 38.901
Rotational 0.889 2.981 25.682
Vibrational 45.383 12.884 6.218
Vibration 1 0.721 1.593 1.206
Vibration 2 0.774 1.449 0.928
Vibration 3 0.775 1.445 0.921
Vibration 4 0.854 1.253 0.662
Vibration 5 0.928 1.091 0.500
Q Log10(Q) Ln(Q)
Total Bot 0.295066D-19 -19.530080 -44.969671
Total V=0 0.578691D+13 12.762447 29.386620
Vib (Bot) 0.123830D-31 -31.907173 -73.468982
Vib (Bot) 1 0.543711D+00 -0.264632 -0.609338
Vib (Bot) 2 0.432025D+00 -0.364492 -0.839273
Vib (Bot) 3 0.429506D+00 -0.367030 -0.845118
Vib (Bot) 4 0.330001D+00 -0.481485 -1.108661
Vib (Bot) 5 0.268351D+00 -0.571297 -1.315459
Vib (V=0) 0.242859D+01 0.385354 0.887310
Vib (V=0) 1 0.123866D+01 0.092953 0.214032
Vib (V=0) 2 0.116079D+01 0.064754 0.149102
Vib (V=0) 3 0.115915D+01 0.064139 0.147685
Vib (V=0) 4 0.109908D+01 0.041030 0.094476
Vib (V=0) 5 0.106746D+01 0.028352 0.065283
Electronic 0.100000D+01 0.000000 0.000000
Translational 0.260582D+08 7.415944 17.075842
Rotational 0.914428D+05 4.961149 11.423469
xxx
IR Spectrum
33 33 1 1 11 1 1 1
44 22 9 7 44 1 1 0 99 8 77 66 5 4 44 3
10 53 1 7 00 9 1 3 52 4 31 22 7 9 11 4
04 38 0 8 66 4 6 8 70 8 79 73 2 9 10 1
XX XX X X XX X X X X X XX X X XX
X X X X XX X X
X X XX X X
X X XX X X
X X XX X X
X XX X X
X XX X X
X XX X X
XX X X
XX X X
XX X X
XX X X
X X
X
X
X
X
X
X
X
***** Axes restored to original set *****
-------------------------------------------------------------------
Center Atomic Forces (Hartrees/Bohr)
Number Number X Y Z
-------------------------------------------------------------------
1 6 -0.000037490 0.000042668 0.000000009
2 6 -0.000042338 -0.000040031 0.000000228
3 6 -0.000001919 -0.000007643 -0.000002528
4 1 0.000000620 0.000000179 -0.000000760
5 6 -0.000000799 0.000007727 0.000001416
6 1 0.000000469 0.000000022 0.000000879
7 6 0.000041652 0.000002279 -0.000001435
8 6 0.000041819 -0.000005775 0.000002811
9 1 -0.000000834 0.000001750 0.000000041
10 1 -0.000001179 -0.000001176 -0.000000661
-------------------------------------------------------------------
Cartesian Forces: Max 0.000042668 RMS 0.000018523
Z-matrix is all fixed cartesians, so copy forces.
Force constants in Cartesian coordinates:
1 2 3 4 5
1 0.113260D+01
2 -0.102656D-01 0.184031D-01
3 -0.402149D-04 0.000000D+00 0.483564D-01
4 -0.351803D-01 0.523272D-01 -0.313887D-05 0.113258D+01
5 -0.523034D-01 0.121430D+00 -0.797633D-05 0.101428D-01 0.184086D-01
6 0.439570D-05 -0.105883D-04 -0.172035D-01 -0.259271D-04 0.247465D-05
7 -0.581319D-01 0.251622D-01 0.000000D+00 -0.212997D-01 -0.251510D-01
8 -0.148940D-01 0.336613D-01 -0.244010D-05 -0.294523D-01 -0.432570D-01
9 0.264935D-05 -0.274523D-05 0.775258D-02 0.292318D-05 0.418471D-05
10 -0.472079D-02 -0.170465D-02 0.000000D+00 0.863568D-03 -0.626530D-03
11 -0.468545D-02 -0.189546D-02 0.000000D+00 0.725001D-04 0.333079D-03
12 0.000000D+00 0.000000D+00 -0.131802D-02 0.000000D+00 0.000000D+00
13 -0.212911D-01 0.251477D-01 -0.164864D-05 -0.581344D-01 -0.251500D-01
14 0.294498D-01 -0.432636D-01 0.309232D-05 0.149069D-01 0.336632D-01
15 -0.159535D-05 0.305943D-05 0.905861D-02 0.000000D+00 -0.155767D-05
16 0.863655D-03 0.626330D-03 0.000000D+00 -0.472011D-02 0.170505D-02
17 -0.724615D-04 0.333174D-03 0.000000D+00 0.468573D-02 -0.189622D-02
18 0.000000D+00 0.000000D+00 -0.285717D-02 0.000000D+00 0.000000D+00
19 0.328895D-01 -0.861508D-01 0.517784D-05 -0.670595D+00 -0.780692D-01
20 0.151214D-01 -0.391294D-01 0.239545D-05 -0.137925D+00 -0.335591D-01
21 -0.185008D-05 0.450928D-05 0.101835D-02 0.229063D-04 0.145439D-05
22 -0.670587D+00 0.781293D-01 0.153871D-04 0.329007D-01 0.861462D-01
23 0.137989D+00 -0.335745D-01 -0.393832D-05 -0.151327D-01 -0.391411D-01
24 0.100428D-04 -0.241421D-05 -0.331243D-01 0.000000D+00 0.106032D-05
25 0.800861D-04 -0.195470D-02 0.000000D+00 -0.376493D+00 0.813535D-01
26 0.108256D-01 -0.163201D-01 0.000000D+00 0.111202D+00 -0.396647D-01
27 0.000000D+00 0.104664D-05 0.192426D-02 0.225445D-05 0.000000D+00
28 -0.376517D+00 -0.813170D-01 0.245586D-04 0.790835D-04 0.195260D-02
29 -0.111165D+00 -0.396443D-01 0.714074D-05 -0.108274D-01 -0.163165D-01
30 0.272255D-04 0.611129D-05 -0.136072D-01 0.000000D+00 0.101544D-05
6 7 8 9 10
6 0.483588D-01
7 0.258849D-05 0.705869D+00
8 0.424221D-05 -0.460577D-01 0.588768D+00
9 0.905855D-02 -0.330507D-05 -0.369718D-04 0.102799D+00
10 0.000000D+00 -0.285820D+00 0.126131D+00 -0.638551D-05 0.302990D+00
11 0.000000D+00 0.125102D+00 -0.114318D+00 0.501035D-05 -0.129733D+00
12 -0.285722D-02 -0.573427D-05 0.491143D-05 -0.263491D-01 0.620481D-05
13 0.304098D-05 -0.911449D-01 -0.408222D-01 0.455255D-05 0.198263D-02
14 -0.204832D-05 0.407920D-01 -0.308877D+00 0.215960D-04 -0.418127D-02
15 0.775287D-02 -0.214961D-05 0.238001D-04 -0.478619D-01 0.000000D+00
16 0.000000D+00 0.197941D-02 0.417892D-02 0.000000D+00 0.123306D-02
17 0.000000D+00 -0.265590D-01 -0.154387D-01 0.220065D-05 -0.180179D-03
18 -0.131763D-02 0.230757D-05 0.000000D+00 0.430601D-02 0.000000D+00
19 0.189059D-04 0.116052D-01 0.829980D-01 -0.639869D-05 0.161752D-02
20 0.254021D-05 0.145037D-01 -0.296588D-01 0.182703D-05 -0.274305D-03
21 -0.331261D-01 -0.163462D-05 0.000000D+00 0.963117D-03 0.000000D+00
22 -0.657247D-05 -0.262581D+00 -0.854903D-01 0.645333D-05 -0.179853D-01
23 0.305523D-05 -0.107877D+00 -0.111459D+00 0.506420D-05 0.106093D-01
24 0.101878D-02 0.842153D-05 0.463073D-05 -0.501071D-01 0.000000D+00
25 0.367185D-05 0.105549D-02 0.466073D-03 0.000000D+00 -0.203044D-04
26 0.000000D+00 0.180624D-02 0.234156D-02 0.000000D+00 -0.583028D-04
27 -0.136082D-01 0.000000D+00 0.000000D+00 -0.150616D-02 0.000000D+00
28 0.000000D+00 -0.153109D-02 0.294245D-02 0.000000D+00 -0.140072D-03
29 0.177133D-05 -0.172125D-02 -0.176161D-02 0.000000D+00 0.181094D-04
30 0.192375D-02 0.000000D+00 0.000000D+00 0.945092D-03 0.000000D+00
11 12 13 14 15
11 0.124592D+00
12 -0.606196D-05 0.207232D-01
13 0.265566D-01 -0.224513D-05 0.705880D+00
14 -0.154414D-01 0.136178D-05 0.460416D-01 0.588755D+00
15 0.000000D+00 0.430599D-02 -0.226497D-04 -0.416346D-04 0.102800D+00
16 0.180207D-03 0.000000D+00 -0.285855D+00 -0.126107D+00 0.189909D-04
17 0.151064D-02 0.000000D+00 -0.125077D+00 -0.114283D+00 0.115945D-04
18 0.000000D+00 -0.741991D-02 0.184625D-04 0.120652D-04 -0.263502D-01
19 0.551715D-03 0.000000D+00 -0.262554D+00 0.855110D-01 0.000000D+00
20 -0.351815D-02 0.117044D-05 0.107897D+00 -0.111486D+00 0.144984D-05
21 0.114118D-05 0.965304D-02 0.000000D+00 0.157971D-05 -0.501069D-01
22 -0.174074D-01 0.142969D-05 0.115926D-01 -0.830048D-01 0.564632D-05
23 0.887190D-02 0.000000D+00 -0.145082D-01 -0.296470D-01 0.252436D-05
24 0.000000D+00 0.106408D-03 0.000000D+00 0.429252D-05 0.962554D-03
25 -0.129547D-03 0.000000D+00 -0.153157D-02 -0.294265D-02 0.000000D+00
26 -0.264252D-03 0.000000D+00 0.172095D-02 -0.176203D-02 0.000000D+00
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28 -0.507346D-03 0.000000D+00 0.105515D-02 -0.465907D-03 0.000000D+00
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30 0.000000D+00 0.117486D-02 0.000000D+00 0.000000D+00 -0.150623D-02
16 17 18 19 20
16 0.303026D+00
17 0.129708D+00 0.124556D+00
18 -0.199778D-04 -0.128606D-04 0.207237D-01
19 -0.179841D-01 0.174109D-01 0.000000D+00 0.976776D+00
20 -0.106055D-01 0.887093D-02 0.000000D+00 0.335847D-02 0.236466D+00
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25 -0.140039D-03 0.507437D-03 0.000000D+00 -0.450416D-02 0.106832D-01
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30 0.000000D+00 0.000000D+00 0.198046D-02 0.000000D+00 0.000000D+00
21 22 23 24 25
21 0.659784D-01
22 0.179994D-05 0.976796D+00
23 0.233535D-05 -0.343393D-02 0.236455D+00
24 0.547759D-02 -0.219379D-04 -0.987814D-05 0.659777D-01
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26 0.000000D+00 -0.471324D-02 0.186833D-02 0.000000D+00 -0.881669D-01
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29 0.000000D+00 0.327504D-01 0.663278D-03 -0.109262D-05 -0.151576D-03
30 0.586493D-03 -0.284740D-05 0.000000D+00 -0.551147D-03 0.000000D+00
26 27 28 29 30
26 0.521482D-01
27 0.000000D+00 0.109397D-01
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29 0.857358D-03 0.000000D+00 0.881311D-01 0.521279D-01
30 0.000000D+00 -0.188543D-02 -0.254300D-04 -0.765349D-05 0.109393D-01
Leave Link 716 at Tue Feb 24 16:16:42 2015, MaxMem= 655360000 cpu: 0.2
(Enter /opt/g09/l103.exe)
GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad
Berny optimization.
Search for a local minimum.
Step number 1 out of a maximum of 2
All quantities printed in internal units (Hartrees-Bohrs-Radians)
Second derivative matrix not updated -- analytic derivatives used.
Eigenvalues --- -0.12913 0.01123 0.01686 0.02518 0.02799
Eigenvalues --- 0.03183 0.03291 0.05318 0.07362 0.09080
Eigenvalues --- 0.10584 0.12888 0.14869 0.16075 0.17845
Eigenvalues --- 0.25987 0.43455 0.47866 0.68393 0.85568
Eigenvalues --- 1.03885 1.04708 1.72926 1.91564
Eigenvalue 1 is -1.29D-01 should be greater than 0.000000 Eigenvector:
Y1 Y2 X10 X9 X3
1 0.68852 -0.68850 0.12011 0.12009 -0.06359
X5 Y5 Y3 Y8 Y7
1 -0.06359 0.05635 -0.05635 -0.04354 0.04351
Angle between quadratic step and forces= 49.89 degrees.
Linear search not attempted -- first point.
TrRot= -0.000005 -0.000004 0.000003 0.000000 0.000001 0.000000
Variable Old X -DE/DX Delta X Delta X Delta X New X
(Linear) (Quad) (Total)
X1 -2.29368 -0.00004 0.00000 -0.00002 -0.00003 -2.29371
Y1 -1.90133 0.00004 0.00000 0.00034 0.00033 -1.90100
Z1 0.00019 0.00000 0.00000 0.00001 0.00002 0.00021
X2 -2.29340 -0.00004 0.00000 -0.00006 -0.00007 -2.29347
Y2 1.90158 -0.00004 0.00000 -0.00031 -0.00031 1.90127
Z2 -0.00009 0.00000 0.00000 0.00000 0.00001 -0.00008
X3 2.31492 0.00000 0.00000 0.00000 0.00000 2.31492
Y3 -1.32315 -0.00001 0.00000 -0.00004 -0.00005 -1.32320
Z3 0.00006 0.00000 0.00000 -0.00002 -0.00002 0.00005
X4 4.12169 0.00000 0.00000 0.00003 0.00003 4.12172
Y4 -2.28780 0.00000 0.00000 -0.00001 -0.00001 -2.28782
Z4 0.00012 0.00000 0.00000 -0.00004 -0.00004 0.00007
X5 2.31510 0.00000 0.00000 -0.00001 -0.00001 2.31509
Y5 1.32287 0.00001 0.00000 0.00003 0.00002 1.32289
Z5 -0.00016 0.00000 0.00000 0.00001 0.00001 -0.00015
X6 4.12200 0.00000 0.00000 0.00001 0.00000 4.12200
Y6 2.28727 0.00000 0.00000 0.00002 0.00002 2.28729
Z6 -0.00030 0.00000 0.00000 0.00003 0.00003 -0.00027
X7 0.00042 0.00004 0.00000 0.00002 0.00001 0.00043
Y7 2.60147 0.00000 0.00000 -0.00003 -0.00003 2.60144
Z7 -0.00018 0.00000 0.00000 -0.00001 -0.00001 -0.00019
X8 0.00007 0.00004 0.00000 0.00004 0.00003 0.00010
Y8 -2.60143 -0.00001 0.00000 -0.00002 -0.00002 -2.60145
Z8 0.00017 0.00000 0.00000 0.00003 0.00003 0.00020
X9 -4.25196 0.00000 0.00000 0.00001 0.00000 -4.25196
Y9 2.42455 0.00000 0.00000 0.00016 0.00016 2.42471
Z9 -0.00007 0.00000 0.00000 -0.00001 0.00000 -0.00007
X10 -4.25230 0.00000 0.00000 0.00004 0.00003 -4.25227
Y10 -2.42408 0.00000 0.00000 -0.00010 -0.00011 -2.42419
Z10 0.00033 0.00000 0.00000 -0.00004 -0.00003 0.00030
Item Value Threshold Converged?
Maximum Force 0.000043 0.000450 YES
RMS Force 0.000019 0.000300 YES
Maximum Displacement 0.000332 0.001800 YES
RMS Displacement 0.000093 0.001200 YES
Predicted change in Energy=-4.163587D-08
Optimization completed.
-- Stationary point found.
GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad
Leave Link 103 at Tue Feb 24 16:16:42 2015, MaxMem= 655360000 cpu: 0.5
(Enter /opt/g09/l9999.exe)
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IN THIS SHORT LIFE
THAT ONLY LASTS AN HOUR
HOW MUCH, HOW LITTLE, IS WITHIN OUR POWER....
EMILY DICKINSON BOLTS OF MELODY NO. 521
Job cpu time: 0 days 0 hours 17 minutes 2.2 seconds.
File lengths (MBytes): RWF= 672 Int= 0 D2E= 0 Chk= 2 Scr= 1
Normal termination of Gaussian 09 at Tue Feb 24 16:16:42 2015.